diff --git a/public/app/plugins/datasource/tempo/package.json b/public/app/plugins/datasource/tempo/package.json
index b9248534a4f..409886cb0d2 100644
--- a/public/app/plugins/datasource/tempo/package.json
+++ b/public/app/plugins/datasource/tempo/package.json
@@ -7,7 +7,7 @@
     "@emotion/css": "11.13.5",
     "@grafana/data": "workspace:*",
     "@grafana/e2e-selectors": "workspace:*",
-    "@grafana/lezer-traceql": "0.0.21",
+    "@grafana/lezer-traceql": "0.0.22",
     "@grafana/monaco-logql": "^0.0.8",
     "@grafana/o11y-ds-frontend": "workspace:*",
     "@grafana/plugin-ui": "0.10.5",
diff --git a/public/app/plugins/datasource/tempo/traceql/autocomplete.ts b/public/app/plugins/datasource/tempo/traceql/autocomplete.ts
index 1c4e13fd611..906d96416d6 100644
--- a/public/app/plugins/datasource/tempo/traceql/autocomplete.ts
+++ b/public/app/plugins/datasource/tempo/traceql/autocomplete.ts
@@ -128,6 +128,7 @@ export class CompletionProvider implements monacoTypes.languages.CompletionItemP
       detail: 'Negated regular expression',
     },
   ];
+  // https://grafana.com/docs/tempo/latest/traceql/#structural
   static readonly structuralOps: MinimalCompletionItem[] = [
     {
       label: '>>',
@@ -164,6 +165,78 @@ export class CompletionProvider implements monacoTypes.languages.CompletionItemP
       documentation:
         'Sibling operator. Checks that spans matching {condA} and {condB} are siblings of the same parent span.',
     },
+    // Union structural operators
+    {
+      label: '&>>',
+      insertText: '&>>',
+      detail: 'Union Descendant',
+      documentation:
+        'The descendant operator (>>) looks for spans matching {condB} that are descendants of a span matching {condA}',
+    },
+    {
+      label: '&>',
+      insertText: '&>',
+      detail: 'Union Child',
+      documentation:
+        'The child operator (>) looks for spans matching {condB} that are direct child spans of a parent matching {condA}',
+    },
+    {
+      label: '&<<',
+      insertText: '&<<',
+      detail: 'Union Ancestor',
+      documentation:
+        'The ancestor operator (<<) looks for spans matching {condB} that are ancestor of a span matching {condA}',
+    },
+    {
+      label: '&<',
+      insertText: '&<',
+      detail: 'Union Parent',
+      documentation:
+        'The parent operator (<) looks for spans matching {condB} that are direct parent spans of a child matching {condA}',
+    },
+    {
+      label: '&~',
+      insertText: '&~',
+      detail: 'Union Sibling',
+      documentation:
+        'The sibling operator (~) looks at spans matching {condB} that have at least one sibling matching {condA}',
+    },
+    // Negated structural operators
+    {
+      label: '!>>',
+      insertText: '!>>',
+      detail: 'Not Descendant',
+      documentation:
+        'The not-descendant operator (!>>) looks for spans matching {condB} that are not descendant spans of a parent matching {condA}',
+    },
+    {
+      label: '!>',
+      insertText: '!>',
+      detail: 'Not Child',
+      documentation:
+        'The not-child operator (!>) looks for spans matching {condB} that are not direct child spans of a parent matching {condA}',
+    },
+    {
+      label: '!<<',
+      insertText: '!<<',
+      detail: 'Not Ancestor',
+      documentation:
+        'The not-ancestor operator (!<<) looks for spans matching {condB} that are not ancestor spans of a child matching {condA}',
+    },
+    {
+      label: '!<',
+      insertText: '!<',
+      detail: 'Not Parent',
+      documentation:
+        'The not-parent operator (!<) looks for spans matching {condB} that are not direct parent spans of a child matching {condA}',
+    },
+    {
+      label: '!~',
+      insertText: '!~',
+      detail: 'Not Sibling',
+      documentation:
+        'The not-sibling operator (!~) looks for spans matching {condB} that do not have at least one sibling matching {condA}',
+    },
   ];
 
   static readonly spansetOps: MinimalCompletionItem[] = [
diff --git a/yarn.lock b/yarn.lock
index bab3b3d8e73..c2d92d559fb 100644
--- a/yarn.lock
+++ b/yarn.lock
@@ -2823,7 +2823,7 @@ __metadata:
     "@emotion/css": "npm:11.13.5"
     "@grafana/data": "workspace:*"
     "@grafana/e2e-selectors": "workspace:*"
-    "@grafana/lezer-traceql": "npm:0.0.21"
+    "@grafana/lezer-traceql": "npm:0.0.22"
     "@grafana/monaco-logql": "npm:^0.0.8"
     "@grafana/o11y-ds-frontend": "workspace:*"
     "@grafana/plugin-configs": "npm:12.1.0-pre"
@@ -3178,12 +3178,12 @@ __metadata:
   languageName: node
   linkType: hard
 
-"@grafana/lezer-traceql@npm:0.0.21":
-  version: 0.0.21
-  resolution: "@grafana/lezer-traceql@npm:0.0.21"
+"@grafana/lezer-traceql@npm:0.0.22":
+  version: 0.0.22
+  resolution: "@grafana/lezer-traceql@npm:0.0.22"
   peerDependencies:
     "@lezer/lr": ^1.4.2
-  checksum: 10/de27346b3f7e45cc10fae18e7172c7686a10d6979b057a33e72f3d4aeca498b7c5ba80202f1e59207f417b69c3f1703bef313dbde155b7a6ee211726d665f085
+  checksum: 10/e7f640e902d0738c72950a7584b5ceed68114582eb9c33546bf3fbc938baf7a460b93cd9b90e65a0d8f16a3870ecc282c6ecc12a6c321232247abc05111662df
   languageName: node
   linkType: hard